Silicones from Dow CorningWe help you invent the future.
Log In | Profile/Preferences | Customer Support | Contact Us
Global (English). Change
Products             Technical Library             Solutions             Premier Services             About Dow Corning
Site Search
Silicon Technology

The Basics of Silicon Chemistry


Silicones


Silicones are synthetic polymers made from the products of nature. Although “silicone” is often used as a generic term for nearly all substances that contain a silicon atom, it is more properly described as an entirely synthetic polymer containing a Si-O backbone. To this backbone, organic groups are frequently attached to the silicon atoms via a Si-C bond.

This general description defines the broad class of polymers known as silicones. The most common example is poly(dimethylsiloxane) or PDMS. This polymer has a repeating (CH3)2SiO unit. These materials are the basic building blocks of the silicone industry. Depending upon the number of repeat units in the polymer chain and the degree of cross-linking ("tying" the polymer chains together), at least six classes of commercially important products can be produced:
  • Fluids
  • Emulsions
  • Compounds
  • Lubricants
  • Resins
  • Elastomers or rubbers
Single polymer strand of PDMS
This is a single polymer strand of poly(dimethylsiloxane) or PDMS. The chain is made up of an alternating Si-O-Si backbone, with each silicon atom bearing two methyl groups. This strand has a molecular weight of nearly 1,200 daltons (amu). In a typical PDMS, a distribution of chain lengths centers around an average molecular weight or size. Depending on how the polymer is manufactured, it may also contain some cyclic siloxane structures. The molecular weight for PDMS can be as small as a few hundred daltons to several hundreds of thousands.

Where do silicones come from?

Silicones are made from silicon and methyl chloride in a process known as the “direct reaction” or “direct process.” This reaction between silicon and our recycled reagents yields methyl chlorosilanes. They are distilled (purified), and the dimethyldichlorosilane is hydrolyzed to give PDMS. This product can be formulated or finished into thousands of different products, which are sold to every major industrial segment.

How are silicones used?

Silicones are highly valued materials because they have a combination of physical properties not found in other polymers. They have outstanding heat stability and can be used in applications where organic materials would melt or decompose. Many silicones seem to be impervious to the effects of aging, weather, sunlight, moisture, heat, cold, and some chemical assaults. Some silicones are used to stick, bond, or couple things together – a glue, if you please.

However, unique surface properties make silicones really different from other materials. The low surface tension of silicone fluids make them ideal for applications such as:

• Paper release agents
• Fiber lubricants
• Textile hand modifiers
• Mold release agents
• Antifouling materials
• Water repellents

In fact, silicones have been used as foam-control agents, anticaking aids, corrosion inhibitors, emulsifiers, lubricants, conditioners, and gloss enhancers – all because of their unique surface properties.

These are just a few of the thousands of current applications for silicones. The diversity of silicone application is already remarkable, but it is only the beginning. Dow Corning’s research and development groups are constantly discovering new applications for silicones, silicone-modified organics, and silicon-based materials. The future of silicon chemistry promises to be more exciting than ever before.

Learn more about:

Siloxane polymerization

Silanes and intermediates

Evolution of silicon science

Gift Bows
Gift bows are easy to use, as are thousands of peel-off products, because a silicon-based coating makes release easy and clean.
< back to The Basics of Silicon Chemistry Home Page  
Media Center    |    Careers    |    Site Map    |    Other Dow Corning Websites
Using this website means you understand our Privacy Statement and agree to our Terms & Conditions.
©2000 - 2008 Dow Corning Corporation. All rights reserved. Dow Corning is a registered trademark of Dow Corning Corporation. We help you invent the future is a trademark of Dow Corning Corporation.